m-Chloroperbenzoic acid → HCID 86735261, compound

HRID 461408Notes

Reaction equation

HRID 461408 reaction equation
[Br:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.ClC1C=CC=C(C(OO)=[O:19])C=1>C(Cl)(Cl)Cl>[Br:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]2[O:19][CH:7]2[CH:6]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 54095446HCID 54095446, compound

Product 1

HCID 86735261HCID 86735261, compoundYield 87.1%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The mixture of 5.1 g of p-bromoallylbenzene, 8.5 g of m-chloroperbenzoic acid and 200 ml of chloroform was allowed to stand at about 5° C for 7 days. The resulting mixture was washed with 10% sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain 4.8 g (yield 85%) of p-bromoallylbenzene oxide.

Workup

  1. washThe resulting mixture was washed with 10% sodium hydroxide solution, water, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated

Sources & evidence

ORD record
ord-8c5f5fd81b0a406d9e481905f6382463
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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