m-Chloroperbenzoic acid → HCID 86735266, compound

HRID 461411Notes

Reaction equation

HRID 461411 reaction equation
[CH2:1]([CH:3]=[CH:4][CH2:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH3:2].ClC1C=CC=C(C(OO)=[O:20])C=1>C(Cl)(Cl)Cl>[CH2:1]([CH:3]=[CH:4][CH2:5][C:6]1[CH:11]=[CH:10][CH:9]2[O:20][CH:8]2[CH:7]=1)[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 53907371HCID 53907371, compound

Product 1

HCID 86735266HCID 86735266, compoundYield 43%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

3.8 g of p-ethylallylbenzene was added to 5.9 g of m-chloroperbenzoic acid dissolved in 70 ml of chloroform and the mixture was allowed to stand at about 5° C for 4 days. The resulting mixture was washed with sodium hydroxide solution, Mohr's salt solution, then water and dried over anhydrous sodium sulfate. The solvent was evaporated and the concentration was distilled under reduced pressure to obtain 1.8 g (yield 43%) of p-ethylallylbenzene oxide having a boiling point of 144° to 143° C/38 mmHg as oily substance.

Workup

  1. washThe resulting mixture was washed with sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. concentrationthe concentration
  5. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-991409a715754ed78a9e374ef91f6e0e
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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