Morpholine → HCID 515314, compound

HRID 461957Notes

Reaction equation

HRID 461957 reaction equation
Cl[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([C:8]1[CH:20]=[CH:19][C:18]2[C:17]3[C:12](=[CH:13][C:14]([C:21](=[O:27])[CH2:22][CH2:23][CH2:24][CH2:25]Cl)=[CH:15][CH:16]=3)[CH2:11][C:10]=2[CH:9]=1)=[O:7].[NH:28]1[CH2:33][CH2:32][O:31][CH2:30][CH2:29]1>>[O:31]1[CH2:32][CH2:33][N:28]([CH2:2][CH2:3][CH2:4][CH2:5][C:6]([C:8]2[CH:20]=[CH:19][C:18]3[C:17]4[C:12](=[CH:13][C:14]([C:21](=[O:27])[CH2:22][CH2:23][CH2:24][CH2:25][N:28]5[CH2:33][CH2:32][O:31][CH2:30][CH2:29]5)=[CH:15][CH:16]=4)[CH2:11][C:10]=3[CH:9]=2)=[O:7])[CH2:29][CH2:30]1

Participants

3

Reactant 2

HCID 8083MorpholineHCID 21392932HCID 21392932, compound

Product 1

HCID 515314HCID 515314, compound

Procedure

By the procedure of Example 7, 20.2g (0.05 mole) of 2,7-bis(5-chlorovaleryl)fluorene, prepared in Example 2, 34.9g (0.4 mole) of morpholine were reacted to give the desired product which was recrystallized twice from methylene chloride-methanol. M.P. 134°-136.5° C, λmax0.1NHCl 325, Elcm1% 776.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-7fac1c0cccda41b6a943989dd966ae8c
Source dataset
uspto-grants-1977_12
Patent number
US04064347

Reaction notes

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