Hydrogen Peroxide → 6-[4-(3,5-Di-tert.butyl-4-hydroxy-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

HRID 463125Notes

Reaction equation

[C:1]([C:5]1[CH:6]=[C:7]([S:16][CH2:17][CH2:18][CH2:19][CH2:20][O:21][C:22]2[CH:23]=[CH:24][C:25]3[NH:30][C:29](=[O:31])[O:28][C:27]([CH3:33])([CH3:32])[C:26]=3[CH:34]=2)[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].[OH:35]O>>[C:12]([C:9]1[CH:8]=[C:7]([S:16]([CH2:17][CH2:18][CH2:19][CH2:20][O:21][C:22]2[CH:23]=[CH:24][C:25]3[NH:30][C:29](=[O:31])[O:28][C:27]([CH3:33])([CH3:32])[C:26]=3[CH:34]=2)=[O:35])[CH:6]=[C:5]([C:1]([CH3:2])([CH3:3])[CH3:4])[C:10]=1[OH:11])([CH3:15])([CH3:14])[CH3:13]

Participants

Reactant 2

HCID 784Hydrogen Peroxide

HCID 132605226-[4-(3,5-Di-tert.butyl-4-hydroxy-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Product 1

HCID 132605686-[4-(3,5-Di-tert.butyl-4-hydroxy-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Procedure

Prepared analogously to Example 2 from 6-[4-(3,5-ditert.butyl-4-hydroxy-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

Sources & evidence

ORD record: ord-ba11bbafaaaa45238876401545d94847
Source dataset: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04518597

Reaction notes

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