Hydrogen Peroxide → 6-[2-(3,4-Dichloro-phenylsulfinyl)-ethoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

HRID 463144Notes

Reaction equation

[Cl:1][C:2]1[CH:3]=[C:4]([S:9][CH2:10][CH2:11][O:12][C:13]2[CH:14]=[CH:15][C:16]3[NH:21][C:20](=[O:22])[O:19][C:18]([CH3:24])([CH3:23])[C:17]=3[CH:25]=2)[CH:5]=[CH:6][C:7]=1[Cl:8].[OH:26]O>>[Cl:1][C:2]1[CH:3]=[C:4]([S:9]([CH2:10][CH2:11][O:12][C:13]2[CH:14]=[CH:15][C:16]3[NH:21][C:20](=[O:22])[O:19][C:18]([CH3:23])([CH3:24])[C:17]=3[CH:25]=2)=[O:26])[CH:5]=[CH:6][C:7]=1[Cl:8]

Participants

Reactant 2

HCID 784Hydrogen Peroxide

HCID 132605396-[2-(3,4-Dichloro-phenylmercapto)-ethoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Product 1

HCID 132605886-[2-(3,4-Dichloro-phenylsulfinyl)-ethoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Procedure

Prepared analogously to Example 2 from 6-[2-(3,4-dichlorophenylmercapto)-ethoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

Sources & evidence

ORD record: ord-e54151810b1d455cbeddfdcfffc5d2dd
Source dataset: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04518597

Reaction notes

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