Hydrogen Peroxide → 6-[3-(3,4-Dichloro-phenylsulfinyl)-propoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

HRID 463145Notes

Reaction equation

[Cl:1][C:2]1[CH:3]=[C:4]([S:9][CH2:10][CH2:11][CH2:12][O:13][C:14]2[CH:15]=[CH:16][C:17]3[NH:22][C:21](=[O:23])[O:20][C:19]([CH3:25])([CH3:24])[C:18]=3[CH:26]=2)[CH:5]=[CH:6][C:7]=1[Cl:8].[OH:27]O>>[Cl:1][C:2]1[CH:3]=[C:4]([S:9]([CH2:10][CH2:11][CH2:12][O:13][C:14]2[CH:15]=[CH:16][C:17]3[NH:22][C:21](=[O:23])[O:20][C:19]([CH3:24])([CH3:25])[C:18]=3[CH:26]=2)=[O:27])[CH:5]=[CH:6][C:7]=1[Cl:8]

Participants

Reactant 2

HCID 784Hydrogen Peroxide

HCID 132605406-[3-(3,4-Dichloro-phenylmercapto)-propoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Product 1

HCID 132605896-[3-(3,4-Dichloro-phenylsulfinyl)-propoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Procedure

Prepared analogously to Example 2 from 6-[3-(3,4-dichloro-phenylmercapto)-propoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

Sources & evidence

ORD record: ord-83187b77b10f4e0f9576eaa9c224e7eb
Source dataset: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04518597

Reaction notes

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