Hydrogen Peroxide → 6-[3-(3,4-Dimethoxy-phenylsulfinyl)-propoxy]-4-isopropyl-4H-3,1-benzoxazin-2-one

HRID 463164Notes

Reaction equation

[CH3:1][O:2][C:3]1[CH:4]=[C:5]([S:11][CH2:12][CH2:13][CH2:14][O:15][C:16]2[CH:17]=[CH:18][C:19]3[NH:24][C:23](=[O:25])[O:22][CH:21]([CH:26]([CH3:28])[CH3:27])[C:20]=3[CH:29]=2)[CH:6]=[CH:7][C:8]=1[O:9][CH3:10].[OH:30]O>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([S:11]([CH2:12][CH2:13][CH2:14][O:15][C:16]2[CH:17]=[CH:18][C:19]3[NH:24][C:23](=[O:25])[O:22][CH:21]([CH:26]([CH3:27])[CH3:28])[C:20]=3[CH:29]=2)=[O:30])[CH:6]=[CH:7][C:8]=1[O:9][CH3:10]

Participants

Reactant 2

HCID 784Hydrogen Peroxide

HCID 132605494-Isopropyl-6-[3-(3,4-dimethoxy-phenylmercapto)-propoxy]-4H-3,1-benzoxazin-2-one

Product 1

HCID 132605976-[3-(3,4-Dimethoxy-phenylsulfinyl)-propoxy]-4-isopropyl-4H-3,1-benzoxazin-2-one

Procedure

Prepared analogously to Example 2 from 6-[3-(3,4-dimethoxy-phenylmercapto)-propoxy]-4-isopropyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

Sources & evidence

ORD record: ord-77dac7d637754f81bccfa607d16bd27e
Source dataset: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04518597

Reaction notes

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