Hydrogen Peroxide → 7-[4-(4-Acetamido-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

HRID 463200Notes

Reaction equation

[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[CH:29]=[CH:28][C:20]3[C:21]([CH3:27])([CH3:26])[O:22][C:23](=[O:25])[NH:24][C:19]=3[CH:18]=2)=[CH:7][CH:6]=1)(=[O:3])[CH3:2].[OH:30]O>>[C:1]([NH:4][C:5]1[CH:6]=[CH:7][C:8]([S:11]([CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[CH:29]=[CH:28][C:20]3[C:21]([CH3:26])([CH3:27])[O:22][C:23](=[O:25])[NH:24][C:19]=3[CH:18]=2)=[O:30])=[CH:9][CH:10]=1)(=[O:3])[CH3:2]

Participants

Reactant 2

HCID 784Hydrogen Peroxide

HCID 202816727-[4-(4-Acetamido-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Product 1

HCID 202818227-[4-(4-Acetamido-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

Procedure

Prepared analogously to Example 2 from 7-[4-(4-acetamido-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

Sources & evidence

ORD record: ord-ce3ccb81999c4bb9823421e35c3b6d63
Source dataset: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04518597

Reaction notes

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