Hydroxylamine → HCID 178526317, compound

HRID 463612Notes

Reaction equation

HRID 463612 reaction equation
[Cl:1][C:2]1[CH:18]=[C:17]([C:19]([F:22])([F:21])[F:20])[CH:16]=[CH:15][C:3]=1[O:4][C:5]1[CH:14]=[CH:13][C:8]2=[N+:9]([O-:12])[O:10][N:11]=[C:7]2[CH:6]=1.NO.O>CO>[Cl:1][C:2]1[CH:18]=[C:17]([C:19]([F:20])([F:22])[F:21])[CH:16]=[CH:15][C:3]=1[O:4][C:5]1[CH:14]=[CH:13][C:8](=[N:9][OH:12])[C:7](=[N:11][OH:10])[CH:6]=1

Participants

5

Reactant 3

HCID 787HydroxylamineHCID 962WaterHCID 135343365-(2-chloro-4-trifluoromethylphenoxy)benzo-2,1,3-oxadiazole N-oxide

Product 1

HCID 178526317HCID 178526317, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A mixture of 5-(2-chloro-4-trifluoromethylphenoxy)benzo-2,1,3-oxadiazole N-oxide (20.0 g, 61.0 mmol) and hydroxylamine (4.0 g, 120.00 mmol) in 50 ml of methanol is stirred at 45° for 18 hours. The reaction is cooled to RT and 10 ml of water is added. The resulting white solid which precipitates is collected and dried to give 4-(2-chloro-4-trifluoromethylphenoxy)-ortho-benzoquinone dioxime.

Workup

  1. customThe resulting white solid which precipitates
  2. customis collected
  3. customdried

Sources & evidence

ORD record
ord-2c14a03ccadf41f2a7151a69fd82b530
Source dataset
uspto-grants-1985_10
Patent number
US04544400

Reaction notes

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