HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Butanol → HCID 178454803, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | HCID 178476830 | HCID 178476830 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 178454803 | HCID 178454803 | 81.6% |
Reaction Steps
A solution of α-hydroxyethylphosphinic acid (2.2 g) and 1-butanol (5.0 g) in benzene (30 ml) was heated for 3 hours with removal of water through a Dean-Stark apparatus. After cooling, the reaction mixture was washed with water, dried over magnesium sulfate and concentrated in vacuo to give 2.71 g (81.6%) of n-butyl α-hydroxyethylphosphinate (Compound No. 5).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04544652 |
| Source dataset | uspto-grants-1985_10 |
| ORD ID | ord-1d8432d027704c71b7d7c4dea8657e9c |
| Source note | uspto-grants-1985_10 |