反应详情

A solution of 8.45 g of tri(n-butyl)phosphine and 8.33 g of chloromethyl 4-chlorophenyl sulfide in 25 ml of p-dioxane was stirred and refluxed (101°-102° C.) for 20 hours. The mixture was cooled to room temperature and diluted with 100 ml of hexane. The white precipitate was filtered and dried to give 1, as a solid, mp 113°-114° C.

1. temperaturerefluxed (101°-102° C.) for 20 hours
2. filtrationThe white precipitate was filtered
3. customdried
4. customto give 1