Ammonia → HCID 13322003, compound

HRID 464231Notes

Reaction equation

HRID 464231 reaction equation
[CH3:1][S:2]([C:5]1[S:6][CH:7]=[CH:8][C:9]=1[S:10](Cl)(=[O:12])=[O:11])(=[O:4])=[O:3].[NH3:14]>C(OCC)(=O)C>[CH3:1][S:2]([C:5]1[S:6][CH:7]=[CH:8][C:9]=1[S:10]([NH2:14])(=[O:12])=[O:11])(=[O:4])=[O:3]

Participants

4

Reactant 2

HCID 222AmmoniaHCID 13322002HCID 13322002, compound

Product 1

HCID 13322003HCID 13322003, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

To 10 g of (XXVIII) in 200 ml of ethyl acetate was added 5 ml of liquid ammonia with stirring at 0°. The mixture was allowed to attain room temperature, evaporated and the solid product was washed with ice-water. A dried sample of (XXV) had m.p. 242°-244°.

Workup

  1. customto attain room temperature
  2. customevaporated
  3. washthe solid product was washed with ice-water

Sources & evidence

ORD record
ord-bbecb9e66c4e432ea4f66cf0bc200175
Source dataset
uspto-grants-1985_10
Patent number
US04547217

Reaction notes

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