Ethylene → Ethylene

HRID 464499Notes

Reaction equation

HRID 464499 reaction equation
[CH2:1]=[CH:2][CH3:3].[CH2:4]=[CH2:5]>CCCCCC>[CH2:1]=[CH2:2].[CH2:1]=[CH:2][CH3:3].[CH2:2]1[CH:3]2[CH:5]3[CH:4]=[CH:1][CH:2]([CH:5]2[CH:4]=[CH:1]1)[CH2:3]3

Participants

6

Reactant 2

HCID 6325EthyleneHCID 8252Propylene

Product 3

HCID 6325EthyleneHCID 6492DicyclopentadieneHCID 8252Propylene

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

Ethylene, propylene and dicyclopentadiene were solution-polymerized at a temperature of 56° C. and a pressure of 2 atmospheres in the presence of a catalyst composed of a 0.5 mmol/1 hexane solution of VOCl3 and a 2.5 mmole/1 hexane solution of (C2H5)1.5 AlCl1.5. The volume ratio of propylene to ethylene was maintained at 3:2.

Sources & evidence

ORD record
ord-1a3216eca69d442086ed0ce4d713b7c9
Source dataset
uspto-grants-1985_10
Patent number
US04547620

Reaction notes

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