Methyldichlorosilane → Dichloro(3-phenylpropyl)silane

HRID 464561Notes

Reaction equation

HRID 464561 reaction equation
[CH3:1][SiH:2]([Cl:4])[Cl:3].[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[CH2:5]([CH2:1][SiH:2]([Cl:4])[Cl:3])[CH2:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

Participants

3

Reactant 2

HCID 6376MethyldichlorosilaneHCID 7501Styrene

Product 1

HCID 71431464Dichloro(3-phenylpropyl)silane

Procedure

The intermediate isomeric phenethylmethyldichlorosilane was prepared from methyldichorosilane and styrene using the method described by J. L. Speier at pages 435ff of ADVANCES IN ORGANOMETALLIC CHEMISTRY, Academic Press, Edited by F. G. A. Stone and R. West, 17 (1979). It contained approximately 65% of the 2-phenethyl isomer and 35% of the 1-phenethyl isomer.

Sources & evidence

ORD record
ord-fe69b268099946e384d43a86b0316fb7
Source dataset
uspto-grants-1985_10
Patent number
US04548690

Reaction notes

Loading…