Acetic acid, 2-((4-chloro-2,5-dimethylphenyl)thio)- → 4-Chloro-2,5-dimethylbenzenethiol

HRID 465496Notes

Reaction equation

HRID 465496 reaction equation
C(C1C=CC(SC[N+]([O-])=O)=CC=1)(C)(C)C.[Cl:16][C:17]1[C:22]([CH3:23])=[CH:21][C:20]([S:24]CC(O)=O)=[C:19]([CH3:29])[CH:18]=1>>[Cl:16][C:17]1[C:22]([CH3:23])=[CH:21][C:20]([SH:24])=[C:19]([CH3:29])[CH:18]=1

Participants

3

Reactant 2

HCID 66739Acetic acid, 2-((4-chloro-2,5-dimethylphenyl)thio)-HCID 14404080(4-t-Butylphenylthio)nitromethane

Product 1

HCID 1088624-Chloro-2,5-dimethylbenzenethiol

Procedure

The thioether (A) was obtained as an oil having a satisfactory NMR spectrum (200 MHz/CDCl3): 2.33 (s, 3H), 2.42 (s, 3H), 5.37 (s, 2H), 7.26 (s, 1H), 7.35 (s, 1H) from (4-chloro-2,5-dimethylphenylthio)aceti acid, itself obtained from 4-chloro-2,5-dimethylbenzenethiol, in both cases using analogous procedures to those described in Example 13.

Sources & evidence

ORD record
ord-68475e402ba547e0b6f162dbe8161876
Source dataset
uspto-grants-1992_10
Patent number
US05153227

Reaction notes

Loading…