4-(4-Hydroxybutyl)cyclohex-3-ene-1-one → 4-(4-Hydroxybutyl)cyclohexanone

HRID 465552Notes

Reaction equation

HRID 465552 reaction equation
[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][C:6]1[CH2:11][CH2:10][C:9](=[O:12])[CH2:8][CH:7]=1>CC(C)=O.[Pd]>[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH:6]1[CH2:7][CH2:8][C:9](=[O:12])[CH2:10][CH2:11]1

Participants

4

Reactant 1

HCID 102411954-(4-Hydroxybutyl)cyclohex-3-ene-1-one

Product 1

HCID 103297384-(4-Hydroxybutyl)cyclohexanone

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 180AcetoneSolvent

Procedure

To a solution of 4.63 g of 4-(4-hydroxybutyl)-cyclohex-3-ene-1-one in 130 ml acetone is added 0.46 g of 10% palladium on carbon and the suspension is then hydrogenated at 3 atmospheres (=3.04 bar) pressure for 3 h. The catalyst is evaporated to dryness to give 4-(4-hydroxybutyl)-cyclohexanone as an oil.

Workup

  1. customThe catalyst is evaporated to dryness

Sources & evidence

ORD record
ord-df360fff9976427c9665fb4cd578eb11
Source dataset
uspto-grants-1992_10
Patent number
US05153214

Reaction notes

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