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HRID466355

反应详情

EQUATION

反应方程式

HRID 466355 的结构方程式

REACTANTS

反应物

3
反应SMILES：O=C(OOC(=O)c1ccccc1)c1ccccc1
HCID7187

Benzoyl peroxide

C14H10O4

反应SMILES：CC(=O)c1ccc(NS(=O)(=O)c2ccc(C)cc2)cc1
HCID563797

N-(4-Acetylphenyl)-4-methylbenzenesulfonamide

C15H15NO3S

反应SMILES：Cc1ccc(S(=O)(=O)Nc2ccc(C(=O)CBr)cc2)cc1
HCID16637184

N-[4-(Bromoacetyl)phenyl]-4-methylbenzene-1-sulfonamide

C15H14BrNO3S

PRODUCTS

产物

1
反应SMILES：CS(=O)(=O)Nc1ccccc1C(=O)CBr
HCID18380501

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
反应SMILES：CCOCC
溶剂HCID3283

Diethyl Ether

C4H10O

PROCEDURE

实验过程

In a similar manner 4'-(2-bromoacetyl)-p-toluenesulfonanilide, (m.p. 174°-1765° with decomposition,) can be prepared by bromination of 4'-acetyl-p-toluenesulfonanilide (Preparation 1) [See R. H. Vloth, et al., J. Med. Chem. 9, 88 (1966)]. For this preparation anhydrous ether can also be used as solvent; benzoyl peroxide can be used as a catalyst. The product is crystallized from acetonitrile.

WORKUP

后处理

  1. customThe product is crystallized from acetonitrile