HRID467173

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID3571582

Sodium 4-vinylbenzenesulfonate

C8H7NaO3S

结构：C=C(C)C(=O)Oc1ccc(-[n+]2c(C)ccc(CCCCCCCCC)c2C)cc1.[Cl-]

HCID19813589

未命名化合物

PRODUCTS

生成物

结构：C=C(C)C(=O)Oc1ccc(-[n+]2c(C)ccc(CCCCCCCCC)c2C)cc1.C=Cc1ccc(S(=O)(=O)[O-])cc1

HCID19813584

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID11

1,2-Dichloroethane

C2H4Cl2

CONDITIONS

反应条件

温度: 45 °C

PROCEDURE

实验过程

To a 20 percent w/v 1,2-dichloroethane solution of 1-(p-methacryloxyphenyl)-2,6-dimethyl-3-nonylpyridinium chloride is added 150 g of sodium p-styrene sulfonate. The slurry is heated to 45° C. and stirred for 4 hours. The solids are separated from the supernatant liquid and the 1,2-dichloroethane is removed to give an oil of 1-(p-methacryloxyphenyl)-2,6-dimethyl-3-nonylpyridinium p-styrene sulfonate.

WORKUP

后处理

customThe solids are separated from the supernatant liquid
customthe 1,2-dichloroethane is removed

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-cd8c9ae497e04588b70141c5c3d40037
来源数据集: uspto-grants-1992_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05159035
来源说明: uspto-grants-1992_10

反应 SMILES

[Cl-].[C:2]([O:7][C:8]1[CH:13]=[CH:12][C:11]([N+:14]2[C:19]([CH3:20])=[CH:18][CH:17]=[C:16]([CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[C:15]=2[CH3:30])=[CH:10][CH:9]=1)(=[O:6])[C:3]([CH3:5])=[CH2:4].[CH2:31]=[CH:32][C:33]1[CH:38]=[CH:37][C:36]([S:39]([O-:42])(=[O:41])=[O:40])=[CH:35][CH:34]=1.[Na+]>ClCCCl>[CH2:31]=[CH:32][C:33]1[CH:34]=[CH:35][C:36]([S:39]([O-:42])(=[O:41])=[O:40])=[CH:37][CH:38]=1.[C:2]([O:7][C:8]1[CH:13]=[CH:12][C:11]([N+:14]2[C:19]([CH3:20])=[CH:18][CH:17]=[C:16]([CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[C:15]=2[CH3:30])=[CH:10][CH:9]=1)(=[O:6])[C:3]([CH3:5])=[CH2:4]