Methanol → HCID 19813940, compound

HRID 467347Notes

Reaction equation

CO.C(O[CH2:7]/[CH:8]=[CH:9]/[CH2:10][O:11][CH:12]([CH3:14])[CH3:13])(C)C.[CH3:15][CH:16]([OH:18])[CH3:17]>>[CH:12]([O:11][CH2:10][CH2:9][C:8]([O:18][CH:16]([CH3:17])[CH3:15])=[CH2:7])([CH3:13])[CH3:14]

Participants

Reactant 3

HCID 887Methanol

HCID 3776Isopropanol

HCID 19006593HCID 19006593, compound

Product 1

HCID 19813940HCID 19813940, compound

Procedure

A reaction was carried out using the catalyst and according to the procedure described in example 6, except that the methanol was replaced with an equivalent amount of 2-propanol (30 ml). 1.8 mmol of 1,3-diisopropoxy-3-butene and 9.7 mmol of cis + trans 1,4-diisopropoxy-2-butene were obtained.

Sources & evidence

ORD record: ord-d28c0bca32f6411ab58fa71271af107e
Source dataset: uspto-grants-1992_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05159120

Reaction notes

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