Ammonium formate → HCID 82404734, compound

HRID 467513Notes

Reaction equation

HRID 467513 reaction equation
C([O-])=O.[NH4+].[CH3:5][C:6]1[CH:7]=[C:8]2[C:12](=[CH:13][C:14]=1[CH3:15])[NH:11][CH:10]=[C:9]2[C:16]([O:18]CC1C=CC=CC=1)=[O:17]>CO.[Pd]>[CH3:5][C:6]1[CH:7]=[C:8]2[C:12](=[CH:13][C:14]=1[CH3:15])[NH:11][CH:10]=[C:9]2[C:16]([OH:18])=[O:17]

Participants

5

Reactant 2

HCID 2723923Ammonium formateHCID 86672978HCID 86672978, compound

Product 1

HCID 82404734HCID 82404734, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

0.54 g of Pd/C 10% and 16.9 g of ammonium formate are added to a solution of 5 g of the compound obtained in step 2 in 120 ml of MeOH. It is heated under reflux for 2 hours. It is filtered on talc and the filtrate is evaporated.

Workup

  1. temperatureIt is heated
  2. temperatureunder reflux for 2 hours
  3. filtrationIt is filtered on talc
  4. customthe filtrate is evaporated

Sources & evidence

ORD record
ord-11f4acbeeb4c4ea7a1a4992b8aab4b32
Source dataset
uspto-grants-2014_01
Patent number
US08623862B2

Reaction notes

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