HRID468570

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID12373

Hexane, 1,6-diiodo-

C6H12I2

结构：CC1(C)C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)N1CCCCN1C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)C1(C)C

HCID49763837

未命名化合物

PRODUCTS

生成物

结构：CC1(C)C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)N1CCCCCCN1C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)C1(C)C

HCID49763838

未命名化合物

收率 27%

PROCEDURE

实验过程

The experimental protocol used is the same as that described for the synthesis of the compound of Example 1, 1,6-diiodohexane replacing 1,4-dibromobutane. The expected compound is obtained in the form of a light yellow solid with a yield of 27%. Melting point: 187-188° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-3ea8d0c5a6b24f7daeb679b1c6c2cb68
来源数据集: uspto-grants-2014_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08624037B2
来源说明: uspto-grants-2014_01

反应 SMILES

[CH2:1](N1C(C)(C)C(=O)N(C2C=CC([N+]([O-])=O)=C(C(F)(F)F)C=2)C1=O)[CH2:2][CH2:3][CH2:4][N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[C:15]([C:22]([F:25])([F:24])[F:23])[CH:14]=2)[C:6]1=[O:26].I[CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55]I>>[CH2:4]([N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:50]2[CH:55]=[CH:54][C:53]([N+:19]([O-:21])=[O:20])=[C:52]([C:22]([F:23])([F:25])[F:24])[CH:51]=2)[C:6]1=[O:26])[CH2:3][CH2:1][CH2:2][CH2:3][CH2:4][N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[C:15]([C:22]([F:24])([F:23])[F:25])[CH:14]=2)[C:6]1=[O:26]