HRID468578

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：ClC/C=C\CCl$

HCID6432115

(2Z)-1,4-Dichlorobut-2-ene

C4H6Cl2

结构：CC1(C)C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)N1CCCCN1C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)C1(C)C

HCID49763837

未命名化合物

PRODUCTS

生成物

$结构：CC1(C)C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)N1C/C=C\CN1C(=O)N(c2ccc([N+](=O)[O-])c(C(F)(F)F)c2)C(=O)C1(C)C$

HCID87135216

未命名化合物

收率 40%

PROCEDURE

实验过程

The experimental protocol used is the same as that described for the synthesis of the compound of Example 1, cis-1,4-dichloro-2-butene replacing 1.4 dibromobutane. The expected compound is obtained in the form of a pale yellow solid with a yield of 40%. Melting point: 191-193° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4b2fe6b5a50044c2aca6c0af38ce7a54
来源数据集: uspto-grants-2014_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08624037B2
来源说明: uspto-grants-2014_01

反应 SMILES

[CH2:1]([N:27]1[C:31]([CH3:33])([CH3:32])[C:30](=[O:34])[N:29]([C:35]2[CH:40]=[CH:39][C:38]([N+:41]([O-:43])=[O:42])=[C:37]([C:44]([F:47])([F:46])[F:45])[CH:36]=2)[C:28]1=[O:48])[CH2:2][CH2:3][CH2:4][N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[C:15]([C:22]([F:25])([F:24])[F:23])[CH:14]=2)[C:6]1=[O:26].ClC/C=C\CCl>>[CH2:1]([N:27]1[C:31]([CH3:33])([CH3:32])[C:30](=[O:34])[N:29]([C:35]2[CH:40]=[CH:39][C:38]([N+:41]([O-:43])=[O:42])=[C:37]([C:44]([F:47])([F:46])[F:45])[CH:36]=2)[C:28]1=[O:48])/[CH:2]=[CH:3]\[CH2:4][N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[C:15]([C:22]([F:25])([F:23])[F:24])[CH:14]=2)[C:6]1=[O:26]