huagongshe.com
HRID47127

反应详情

EQUATION

反应方程式

HRID 47127 的结构方程式

REACTANTS

反应物

3
结构：CCOCC.FB(F)F
HCID8000

Ethane, 1,1'-oxybis-, compd. with trifluoroborane (1:1)

C4H10BF3O

结构：CCCCCCC(C)(C)c1cc(O)cc(O)c1
HCID91870

5-(1,1-Dimethylheptyl)resorcinol

C15H24O2

结构：CC(=O)OC1(OC(C)=O)C=CC2CC1C2(C)C
HCID20333900

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCCC(C)(C)c1cc(O)c2c(c1)OC(C)(C)[C@@H]1CCC(=O)C[C@@H]21
HCID5284592

未命名化合物

PROCEDURE

实验过程

Following the same procedure as set forth above, (+)-6,6-dimethyl-2,2-diacetoxy-3-norpinene was reacted with 5-(1,1-dimethylheptyl)resorcinol in the presence of boron trifluoride diethyl etherate to afford (-)-trans-1-hydroxy-3-(1,1-dimethylheptyl)-6,6-dimethyl-6,6a,7,8,10,10a-hexahydro-9H-dibenzo[b,d]pyran-9-one.