Phenylboronic Acid → 3-Nitrobiphenyl-2-carbonitrile

HRID 471616Notes

Reaction equation

HRID 471616 reaction equation
FC(F)(F)S(O[C:7]1[CH:12]=[CH:11][CH:10]=[C:9]([N+:13]([O-:15])=[O:14])[C:8]=1[C:16]#[N:17])(=O)=O.[C:20]1(B(O)O)[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>>[N+:13]([C:9]1[CH:10]=[CH:11][CH:12]=[C:7]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:8]=1[C:16]#[N:17])([O-:15])=[O:14]

Participants

3

Reactant 2

HCID 66827Phenylboronic AcidHCID 866574732-Cyano-3-nitrophenyl trifluoromethanesulfonate

Product 1

HCID 539001333-Nitrobiphenyl-2-carbonitrile

Procedure

Prepared as in Example 129c from 2-cyano-3-nitrophenyl trifluoromethanesulfonate (Example 129d) and phenylboronic acid.

Sources & evidence

ORD record
ord-42cc6ce957f944a688e2deb55fe212dd
Source dataset
uspto-grants-2014_01
Patent number
US08633186B2

Reaction notes

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