Potassium Carbonate → HCID 67498122, compound

HRID 473482Notes

Reaction equation

HRID 473482 reaction equation
C(=O)([O-])[O-].[K+].[K+].[C:7]([NH:10][C:11]1[CH:12]=[C:13]([OH:17])[CH:14]=[CH:15][CH:16]=1)(=[O:9])[CH3:8].[CH3:18][O:19][C:20](=[O:32])[C:21]1[CH:26]=[CH:25][C:24]([N+:27]([O-:29])=[O:28])=[CH:23][C:22]=1[CH2:30]Br>CC(C)=O>[CH3:18][O:19][C:20](=[O:32])[C:21]1[CH:26]=[CH:25][C:24]([N+:27]([O-:29])=[O:28])=[CH:23][C:22]=1[CH2:30][O:17][C:13]1[CH:14]=[CH:15][CH:16]=[C:11]([NH:10][C:7](=[O:9])[CH3:8])[CH:12]=1

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 121243-HydroxyacetanilideHCID 15088701Methyl 2-(bromomethyl)-4-nitrobenzoate

Product 1

HCID 67498122HCID 67498122, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

In accordance with general method U, 1.50 g (10.86 mmol) of potassium carbonate are suspended in 15 ml of acetone, 1.80 g (11.90 mmol) of 3-acetamidophenol are then added and the mixture is stirred for 15 min. 2.44 g (8.91 mmol) of (2) are added to the mixture.

Sources & evidence

ORD record
ord-254bf5fa7e3c41f58ca9aca2fcb5c972
Source dataset
uspto-grants-2014_01
Patent number
US08633312B2

Reaction notes

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