Stannous chloride dihydrate → 8-Amino-3-(tetrazol-1-yl)-6H-dibenzo[b,e]oxepin-11-one

HRID 473497Notes

Reaction equation

HRID 473497 reaction equation
O.O.[Sn](Cl)Cl.[N:6]1([C:11]2[CH:12]=[CH:13][C:14]3[C:20](=[O:21])[C:19]4[CH:22]=[CH:23][C:24]([N+:26]([O-])=O)=[CH:25][C:18]=4[CH2:17][O:16][C:15]=3[CH:29]=2)[CH:10]=[N:9][N:8]=[N:7]1>C(O)C>[NH2:26][C:24]1[CH:23]=[CH:22][C:19]2[C:20](=[O:21])[C:14]3[CH:13]=[CH:12][C:11]([N:6]4[CH:10]=[N:9][N:8]=[N:7]4)=[CH:29][C:15]=3[O:16][CH2:17][C:18]=2[CH:25]=1

Participants

4

Reactant 2

HCID 61436Stannous chloride dihydrateHCID 673618033-(Tetrazol-1-yl)-8-nitro-6H-dibenzo[b,e]oxepin-11-one

Product 1

HCID 452807468-Amino-3-(tetrazol-1-yl)-6H-dibenzo[b,e]oxepin-11-one

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

In accordance with general method Y, 1.50 g (6.66 mmol) of tin(II) chloride dihydrate are dissolved in 10 ml of ethanol, and 0.50 g (1.54 mmol) of (20) is added.

Sources & evidence

ORD record
ord-c273b256f850433194ee33d77acdf796
Source dataset
uspto-grants-2014_01
Patent number
US08633312B2

Reaction notes

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