3-Aminopyridine → N-[1-(Methylsulfanyl)-2-nitroethenyl]pyridin-3-amine

HRID 479516Notes

Reaction equation

[NH2:1][C:2]1[CH:3]=[N:4][CH:5]=[CH:6][CH:7]=1.[CH3:8][S:9][C:10](SC)=[CH:11][N+:12]([O-:14])=[O:13]>>[CH3:8][S:9][C:10]([NH:1][C:2]1[CH:3]=[N:4][CH:5]=[CH:6][CH:7]=1)=[CH:11][N+:12]([O-:14])=[O:13]

Participants

Reactant 2

HCID 100093-Aminopyridine

HCID 836231,1-Bis(methylthio)-2-nitroethylene

Product 1

HCID 69142379N-[1-(Methylsulfanyl)-2-nitroethenyl]pyridin-3-amine

Procedure

3-Aminopyridine and 1,1-bis(methylthio)-2-nitroethylene were processed as in Example 54B to provide the desired product.

Sources & evidence

ORD record: ord-e13a301245124ec28dbbcfe300fd1a76
Source dataset: uspto-grants-2003_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06645968B2

Reaction notes

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