Sodium Hydroxide → HCID 23698652, compound

HRID 479883Notes

Reaction equation

HRID 479883 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([SH:9])[CH:5]=[C:6]([Cl:8])[CH:7]=1.[OH-].[Na+:11]>>[Cl:1][C:2]1[CH:3]=[C:4]([S-:9])[CH:5]=[C:6]([Cl:8])[CH:7]=1.[Na+:11]

Participants

3

Reactant 2

HCID 14798Sodium HydroxideHCID 27360963,5-Dichlorobenzenethiol

Product 1

HCID 23698652HCID 23698652, compound

Procedure

A 4-necked, 1-liter flask equipped with a stirrer, a thermometer, a dropping funnel and a condenser tube was charged with 163.1 g (0.824 mole of 3,5-dichlorothiophenol) of the crude 3,5-dichlorothiophenol (purity 90.4%) prepared by the process of Example 1, and 370 g (0.925 mole) of an aqueous solution of 10 wt % sodium hydroxide. After 15 minutes of reaction at 25° C., the reaction mixture was subjected to separation procedure to give an aqueous solution of sodium 3,5-dichlorothiophenolate.

Workup

  1. customA 4-necked, 1-liter flask equipped with a stirrer
  2. customAfter 15 minutes of reaction at 25° C.
  3. customthe reaction mixture was subjected to separation procedure

Sources & evidence

ORD record
ord-94c56e84981c4bc3aa8161102d2df175
Source dataset
uspto-grants-2003_11
Patent number
US06646165B2

Reaction notes

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