p-Chlorothiophenol → HCID 23693160, compound

HRID 479884Notes

Reaction equation

HRID 479884 reaction equation
ClC1C=CC=CC=1.[Cl:8][C:9]1[CH:14]=[CH:13][C:12]([SH:15])=[CH:11][CH:10]=1.[OH-].[K+:17]>>[Cl:8][C:9]1[CH:14]=[CH:13][C:12]([S-:15])=[CH:11][CH:10]=1.[K+:17]

Participants

4

Reactant 3

HCID 7815p-ChlorothiophenolHCID 7964ChlorobenzeneHCID 14797Potassium Hydroxide

Product 1

HCID 23693160HCID 23693160, compound

Procedure

A 4-necked, 1-liter flask equipped with a stirrer, a thermometer, a dropping funnel and a condenser tube was charged with a monochlorobenzene solution (0.871 mole of 4-chlorothiophenol) of 4-chlorothiophenol (13.3% of impurities) prepared by the process of Example 2 and 520 g (0.929 mole) of an aqueous solution of 10 wt % potassium hydroxide. The mixture was reacted at 25° C. for 15 minutes and was subjected to separation procedure to give an aqueous solution of potassium 4-chlorothiophenolate.

Workup

  1. customA 4-necked, 1-liter flask equipped with a stirrer
  2. customThe mixture was reacted at 25° C. for 15 minutes
  3. customwas subjected to separation procedure

Sources & evidence

ORD record
ord-a571f5b52e9940179a2551b3bb20045d
Source dataset
uspto-grants-2003_11
Patent number
US06646165B2

Reaction notes

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