Chlorine → HCID 19063429, compound

HRID 482201Notes

Reaction equation

HRID 482201 reaction equation
[C:1](=[O:19])(SCC)[O:2][CH2:3][O:4][C:5]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])=[O:6].[Cl:20]Cl>>[Cl:20][C:1]([O:2][CH2:3][O:4][C:5]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])=[O:6])=[O:19]

Participants

3

Reactant 2

HCID 24526ChlorineHCID 19063414HCID 19063414, compound

Product 1

HCID 19063429HCID 19063429, compound

Procedure

SO2Cl2 (1.17 g, 8.65 mmol) was added to O-nonylcarbonyloxymethyl S-ethyl carbonothioate (Example 1ad(ii), 2.10 g, 7.22 mmol) in CH2 Cl2 (5 ml) at 0° C. with stirring during 15 min. followed by stirring at ambient temperature for 17 hours. Evaporation of EtSCl at 30° C. and 20 mmHg gave a yellow liquid.

Workup

  1. stirringby stirring at ambient temperature for 17 hours
  2. customEvaporation of EtSCl at 30° C.
  3. custom20 mmHg gave a yellow liquid

Sources & evidence

ORD record
ord-0d8c25e44d7c41799397d78a71d37b32
Source dataset
uspto-grants-1998_08
Patent number
US05795562

Reaction notes

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