反应详情

2 g (5.1 mmol) of methyl 4-[3-(1-adamantyl)-4-hydroxyphenylethynyl]benzoate, 1.1 ml (8.3 mmol) of 6-bromo-1-hexanol, 1.2 g (8.8 mmol) of potassium carbonate, 20 mg of potassium iodide and 100 ml of 2-butanone were introduced into a round-bottomed flask. The reaction mixture was heated at reflux for twelve hours and was evaporated to dryness, the residue was taken up in water and ethyl acetate and the organic phase was separated by settling, dried over magnesium sulfate and evaporated.

1. temperatureThe reaction mixture was heated
2. temperatureat reflux for twelve hours
3. customwas evaporated to dryness
4. customethyl acetate and the organic phase was separated
5. dry with materialdried over magnesium sulfate
6. customevaporated