Benzyl Alcohol → Benzyl trifluoromethanesulfonate

HRID 482862Notes

Reaction equation

HRID 482862 reaction equation
[F:1][C:2]([F:11])([F:10])[S:3]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])=[O:4].[CH2:12](O)[C:13]1C=CC=[CH:15][CH:14]=1.FC(F)(F)S(OS(C(F)(F)F)(=O)=O)(=O)=O>C(Cl)(Cl)(Cl)Cl>[F:11][C:2]([F:10])([F:1])[S:3]([O:6][CH2:7][C:8]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:9]=1)(=[O:4])=[O:5]

Participants

5

Reactant 3

HCID 244Benzyl AlcoholHCID 67749Trifluoromethanesulfonic anhydrideHCID 109322232-Propen-1-yl 1,1,1-trifluoromethanesulfonate

Product 1

HCID 11096711Benzyl trifluoromethanesulfonate

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

Benzyl trifluoromethanesulfonate was prepared in carbon tetrachloride solution and used as a dried solution in Examples 53 through 55, in the same way the 2-propen-1-yl trifluoromethanesulfonate was prepared and used in Examples 41 through 44, starting with benzyl alcohol and trifluoromethanesulfonic anhydride.

Workup

  1. customwas prepared

Sources & evidence

ORD record
ord-19679394f5934066beb5778f15afb1c2
Source dataset
uspto-grants-1986_03
Patent number
US04576905

Reaction notes

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