Acetone → HCID 22990882, compound

HRID 484079Notes

Reaction equation

HRID 484079 reaction equation
[CH:1]1([CH2:7][CH2:8][CH2:9][CH2:10][N:11]2[CH2:16][CH2:15][C:14](=[C:17]3[C:23]4C=[CH:25][CH:26]=[CH:27][C:22]=4C=C[C:19]4[CH:28]=[CH:29][CH:30]=[CH:31][C:18]3=4)[CH2:13][CH2:12]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C[N+]1([O-])CC[O:36]CC1.[CH3:40][C:41]([CH3:43])=[O:42]>[Os](=O)(=O)(=O)=O>[CH:1]1([CH2:7][CH2:8][CH2:9][CH2:10][N:11]2[CH2:16][CH2:15][C:14](=[C:17]3[C:23]4[CH:22]=[CH:27][CH:26]=[CH:25][C:43]=4[C:41]([OH:42])=[C:40]([OH:36])[C:19]4[CH:28]=[CH:29][CH:30]=[CH:31][C:18]3=4)[CH2:13][CH2:12]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

5

Reactant 3

HCID 180Acetone2×HCID 82029Methyl morpholine oxideHCID 9955277HCID 9955277, compound

Product 1

HCID 22990882HCID 22990882, compound

Reagents, catalysts & solvents 1

HCID 30318Osmium TetroxideCatalyst

Procedure

A osmium tetraoxide (0.4 mmol) in acetone was added to the 50% aqueous solution of acetone dissolved in 1-Cyclohexyl-4-[4-(5H-dibenzo[a,d]cyclohepten-5-ylidene)-1-piperidinyl)butane (4.8 mmol) and N-methylmorpholine-N-oxide (7.2 mmol). The mixture was stirred for over night at ambient temperature.

Sources & evidence

ORD record
ord-7b4d07c0c1cf48c19494e6f1b486c3a1
Source dataset
uspto-grants-1993_07
Patent number
US05229400

Reaction notes

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