Triethylamine → HCID 19746946, compound

HRID 484291Notes

Reaction equation

HRID 484291 reaction equation
Cl[P:2]1[O:7][CH2:6][C:5]2([CH2:12][O:11][P:10](Cl)[O:9][CH2:8]2)[CH2:4][O:3]1.[CH2:14]([NH2:32])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31].C([N:35]([CH2:38][CH3:39])CC)C>C1(C)C=CC=CC=1>[CH2:14]([NH:32][P:2]1[O:7][CH2:6][C:5]2([CH2:12][O:11][P:10]([NH:35][CH2:38][CH2:39][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH3:14])[O:9][CH2:8]2)[CH2:4][O:3]1)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 15793OctadecylamineHCID 772022,4,8,10-Tetraoxa-3,9-diphosphaspiro[5.5]undecane, 3,9-dichloro-

Product 1

HCID 19746946HCID 19746946, compoundYield 90.3%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The procedure of Example 1 is repeated using 13.3 g (50 mmol) of 3,9-dichloro-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane, 27.1 g (100 mmol) of octadecylamine and 15 mL (110 mmol) of triethylamine in 350 mL of toluene to give a crude reaction residue. The residue is purified by recrystallization from a mixture of toluene and acetonitrile to give 33 g (90% yield) of the title compound as an off-white solid melting at 67°-70° C.

Workup

  1. customto give a crude
  2. customreaction residue
  3. customThe residue is purified by recrystallization from a mixture of toluene and acetonitrile

Sources & evidence

ORD record
ord-4f0e57a354e94779bd7d26b3ee4cf770
Source dataset
uspto-grants-1993_07
Patent number
US05230816

Reaction notes

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