Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | N,N-Dimethylbenzylamine | HCID 7681 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Styrene | HCID 7501 | 55% |
| Product | trans-Stilbene | HCID 638088 | 9% |
Reaction Steps
1.44 ml (12.5 mmols) of benzoyl chloride, 1.88 ml (12.5 mmols) of N-benzyldimethylamine and 0.0281 g (0.125 mmol) of palladium acetate are added to 25 ml of toluene in a pressure apparatus constructed of glass. The apparatus is flushed with ethylene in order to remove the air. Ethylene is then injected at 10 bar and the mixture is stirred for 4 hours at 120° C. 55% of styrene and 9% of trans-stilbene are formed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04533505 |
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| Source dataset | uspto-grants-1985_08 |
|---|
| ORD ID | ord-3b4ff9d3a9cb4683841ce19326b808e0 |
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| Source note | uspto-grants-1985_08 |
|---|
