Hydrogen Peroxide → (E)-2-[(Dimethylamino)phenylmethylene]-benzo[b]thiophen-3(2H)-one-1-oxide

HRID 485262Notes

Reaction equation

HRID 485262 reaction equation
[CH3:1][N:2](/[C:4](/[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)=[C:5]1\[C:6](=[O:14])[C:7]2[CH:13]=[CH:12][CH:11]=[CH:10][C:8]=2[S:9]\1)[CH3:3].[OH:21]O>C(O)(=O)C>[CH3:3][N:2](/[C:4](/[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)=[C:5]1\[C:6](=[O:14])[C:7]2[CH:13]=[CH:12][CH:11]=[CH:10][C:8]=2[S:9]\1=[O:21])[CH3:1]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 70479181(E)-2-[(Dimethylamino)phenylmethylene]-benzo[b]thiophen-3(2H)-one

Product 1

HCID 70478556(E)-2-[(Dimethylamino)phenylmethylene]-benzo[b]thiophen-3(2H)-one-1-oxide

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Prepared analogous to Example 1 from (E)-2-[(dimethylamino)phenylmethylene]-benzo[b]thiophen-3(2H)-one and perhydrol in glacial acetic acid.

Sources & evidence

ORD record
ord-cb00aadef58c49f380a985fca13bfe53
Source dataset
uspto-grants-1985_08
Patent number
US04536402

Reaction notes

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