HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Dioxide → HCID 20270364, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | HCID 20270349 | HCID 20270349 | — |
| Solvent | Ethyl acetate hexane | HCID 21226206 | — |
| Product | HCID 20270364 | HCID 20270364 | — |
Reaction Steps
A stirred portion (0.63 g, 0.0007 m) of the acid from Step D above in an oxygen-free atmosphere is set in an oil-bath set at 210° C. (and rising to 230° C.) and kept there until carbon dioxide evolution ceases. Chromatography of the residue obtained, using a silica gel column and 25% ethyl acetate/hexane as eluant yields pure ethyl 5-(2,3-dihydro-1H-pyrrolizin-5-oyl)-6-methyl-2,3-dihydro-1H-pyrrolizine-1-carboxylate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04536512 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-164d3fb0bf364a3fa79e0452bdd16c65 |
| Source note | uspto-grants-1985_08 |