HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 8-Nitrodibenzo[b,f]thiepin-3-carboxylic acid 5,5-dioxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | 3-Cyano-8-nitrodibenzo[b,f]thiepin-5,5-dioxide | HCID 20270214 | — |
| Product | 8-Nitrodibenzo[b,f]thiepin-3-carboxylic acid 5,5-dioxide | HCID 13151882 | — |
Reaction Steps
400 Mg. 3-cyano-8-nitrodibenzo[b,f]-thiepin-5,5-dioxide is refluxed in 5 cc. acetic acid and 5 cc. 50% aqueous sulfuric acid for 24 hours. The mixture is cooled down, the crystallized material is filtered, washed with water, dried at 135° C. in vacuum to yield 345 mg. (81.2%) acid, m.p. 310°-312° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04536507 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-c23cc5077431430baefd76d597638745 |
| Source note | uspto-grants-1985_08 |