HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → Benzamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | Benzonitrile | HCID 7505 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Catalyst | Tetrabutylammonium Chloride | HCID 70681 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Benzamide | HCID 2331 | 96% |
Reaction Steps
103.1 Grams of benzonitrile (II-4), 9.51 g of sodium methoxide, 291.5 g of a 35% aqueous hydrogen peroxide solution and 2.78 g of tetra-n-butylammonium chloride were mixed in 309.3 g of methanol. After the completion of the reaction, the formed precipitate was filtered out and washed with water to obtain 116.3 g of benzamide (m.p.: 130° C.) (I-4) in a yield of 96%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04536599 |
| Source dataset | uspto-grants-1985_08 |
| ORD ID | ord-8f3d762f02524216b88920d0f8185b4b |
| Source note | uspto-grants-1985_08 |