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HRID486037

反应详情

EQUATION

反应方程式

HRID 486037 的结构方程式

REACTANTS

反应物

2
结构：N#Cc1ccccc1Br
HCID16272

Benzonitrile, 2-bromo-

C7H4BrN

结构：[CH3][Sn]([CH3])([CH3])[N]=[N+]=[N-]
HCID5104973

Azidotrimethyltin(IV)

C3H9N3Sn

PRODUCTS

生成物

1
结构：[CH3][Sn]([CH3])([CH3])[n]1nnnc1-c1ccccc1Br
HCID20079345

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

To a solution of 1.50 g of o-bromobenzonitrile in 8.0 ml of toluene is added 1.70 g of trimethyltin azide. The reaction mixture is heated to reflux for 18 hours and then allowed to cool to room temperature. The resulting white precipitate is isolated by filtration and used without purification in the next step.

WORKUP

后处理

  1. temperatureThe reaction mixture is heated
  2. temperatureto reflux for 18 hours
  3. customThe resulting white precipitate is isolated by filtration
  4. customused without purification in the next step