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HRID486318

反应详情

EQUATION

反应方程式

HRID 486318 的结构方程式

REACTANTS

反应物

3
反应SMILES：c1c[nH]cn1
HCID795

Imidazole

C3H4N2

反应SMILES：CC(C)(C)[Si](C)(C)Cl
HCID28928

Chloro(1,1-dimethylethyl)dimethylsilane

C6H15ClSi

反应SMILES：OCCCCCCCCBr
HCID162607

1-Octanol, 8-bromo-

C8H17BrO

PRODUCTS

产物

1
反应SMILES：CC(C)(C)[Si](C)(C)OCCCCCCCCBr
HCID10969362

Silane, [(8-bromooctyl)oxy](1,1-dimethylethyl)dimethyl-

C14H31BrOSi

收率 88%

AUXILIARIES

试剂、催化剂与溶剂

1
反应SMILES：CN(C)C=O
溶剂HCID6228

Dimethylformamide

C3H7NO

PROCEDURE

实验过程

One operates as in preparation 13 starting with 3.97 g of 8-bromooctanol, 19 cm3 of dimethylformamide, 1.55 g of imidazole and 3.32 g of dimethyl tertbutyl chlorosilane. After chromatography on silica (eluant: cyclohexane--toluene 8-2), one obtains 5.4 g of the expected product.