Sodium methanethiolate → HCID 15294796, compound

HRID 486609Notes

Reaction equation

HRID 486609 reaction equation
C[O:2][C:3]1[CH:8]=[CH:7][C:6]([S:9]([NH:12][C:13]2[C:14]([NH:19][C:20]3[CH:25]=[CH:24][C:23]([O:26]C)=[CH:22][CH:21]=3)=[N:15][CH:16]=[CH:17][CH:18]=2)(=[O:11])=[O:10])=[CH:5][CH:4]=1.C[S-].[Na+]>CN(C=O)C>[OH:2][C:3]1[CH:8]=[CH:7][C:6]([S:9]([NH:12][C:13]2[C:14]([NH:19][C:20]3[CH:25]=[CH:24][C:23]([OH:26])=[CH:22][CH:21]=3)=[N:15][CH:16]=[CH:17][CH:18]=2)(=[O:10])=[O:11])=[CH:5][CH:4]=1

Participants

4

Reactant 2

HCID 4378561Sodium methanethiolateHCID 15175083HCID 15175083, compound

Product 1

HCID 15294796HCID 15294796, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Conditions

Temperature
100 °C

Procedure

The compound produced in Example 4 was dissolved in DMF and five equivalents of sodium methanethiolate was added to the solution. The resulting solution was heated at 100° C. and treated to obtain the title compound.

Workup

  1. additiontreated

Sources & evidence

ORD record
ord-c76c5e75d2ca4aa88ba1d7b9e6e468ef
Source dataset
uspto-grants-1994_03
Patent number
US05292758

Reaction notes

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