Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 18961046, compound

HRID 487975Notes

Reaction equation

HRID 487975 reaction equation
[O:1]=[C:2]1[NH:6][CH:5]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)[CH:4]([C:13]([OH:15])=O)[O:3]1.[N+]([O-])(O)=O.[N+:20]([O:23][CH2:24][CH2:25][NH2:26])([O-:22])=[O:21].C1(P(N=[N+]=[N-])(C2C=CC=CC=2)=O)C=CC=CC=1>>[N+:20]([O:23][CH2:24][CH2:25][NH:26][C:13]([CH:4]1[O:3][C:2](=[O:1])[NH:6][CH:5]1[C:7]1[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=1)=[O:15])([O-:22])=[O:21]

Participants

4

Reactant 3

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 199401P,P-Diphenylphosphinic azideHCID 11333231HCID 11333231, compound

Product 1

HCID 18961046HCID 18961046, compoundYield 7.5%

Procedure

Following a procedure similar to that described in Example 1, but using 112 mg of 2-oxo-4-phenyloxazolidine-5-carboxylic acid, 110 mg of N-(2-nitrooxyethyl)amine nitrate and 0.24 ml of diphenylphosphoryl azide, 12 mg of the title compound were obtained as colorless crystals, melting at 122°-124° C.

Sources & evidence

ORD record
ord-1828d407960f490a8d7f28db67f24b7c
Source dataset
uspto-grants-1994_03
Patent number
US05298516

Reaction notes

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