Benzyl Bromide → HCID 53802536, compound

HRID 488308Notes

Reaction equation

[CH3:1][O:2][C:3](=[O:26])[C:4]1[CH:9]=[C:8]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:7]=[CH:6][C:5]=1[OH:25].[CH2:27](Br)[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1>>[CH3:1][O:2][C:3](=[O:26])[C:4]1[CH:9]=[C:8]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:7]=[CH:6][C:5]=1[O:25][CH2:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1

Participants

Reactant 2

HCID 7498Benzyl Bromide

HCID 86747714HCID 86747714, compound

Product 1

HCID 53802536HCID 53802536, compoundYield 82%

Procedure

The reaction of 2-(hydroxy-5-(tetradecyloxy)benzoic acid methyl ester with benzyl bromide under conditions described in Example 59 gave 2-(phenylmethoxy)-5-(tetradecyloxy)benzoic acid methyl ester (82% yield, mp 43°-46°).

Sources & evidence

ORD record: ord-ab38d0a9153d41e4bcd131c067377a33
Source dataset: uspto-grants-1994_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05298652

Reaction notes

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