Water → HCID 86608401, compound

HRID 490047Notes

Reaction equation

HRID 490047 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[S:9]([O:14]C)([O:12][CH3:13])(=[O:11])=[O:10].O>C(OCC)C>[S:9]([O-:14])([OH:12])(=[O:11])=[O:10].[CH3:8][S+:7]([CH3:13])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 962WaterHCID 6497Dimethyl SulfateHCID 7520Thioanisole

Product 1

HCID 86608401HCID 86608401, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6.2 g (0.05 mole) of thioanisole and 6.9 g (0.055 mole) of dimethyl sulfate were stirred for 12 hours at room temperature. 100 g of water and 50 ml of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, dimethylphenylsulfonium hydrogen sulfate.

Workup

  1. customseparated into two layers

Sources & evidence

ORD record
ord-782fb310ecb7419493e783160f4f1090
Source dataset
uspto-grants-2009_05
Patent number
US07527912B2

Reaction notes

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