Benzyl Isothiocyanate → HCID 11574332, compound

HRID 491696Notes

Reaction equation

HRID 491696 reaction equation
[CH2:1]([N:8]=[C:9]=[S:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:11]1([CH:17]([N:24]=[C:25]=[O:26])[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.C([O:29]CC)C>>[CH2:1]([N:8]1[C:9](=[O:29])[S:10][N:24]([CH:17]([C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=2)[C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=2)[C:25]1=[O:26])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 2346Benzyl IsothiocyanateHCID 3283Diethyl EtherHCID 4250935(Isocyanatomethylene)dibenzene

Product 1

HCID 11574332HCID 11574332, compound

Procedure

Reagents: Benzylisothiocyanate (6.5 mmol, 0.85 mL), diphenylmethyl-isocyanate (6.5 mmol, 1.23 mL) and SO2Cl2 (6.5 mmol, 0.52 mL) in diethyl ether (25 mL). Isolation: filtration of reaction mixture. Purification: recrystallization from MeOH.

Workup

  1. filtrationIsolation: filtration of reaction mixture
  2. customPurification
  3. customrecrystallization from MeOH

Sources & evidence

ORD record
ord-519719dd1a9940a68a2634fb67d5c1b8
Source dataset
uspto-grants-2009_05
Patent number
US07531561B2

Reaction notes

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