Benzyl Isothiocyanate → HCID 11523651, compound

HRID 491698Notes

Reaction equation

HRID 491698 reaction equation
[CH2:1]([N:8]=[C:9]=[S:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:11]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[N:24]=[C:25]=[O:26])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.C([O:29]CC)C>>[CH2:1]([N:8]1[C:9](=[O:29])[S:10][N:24]([C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][C:18]=2[CH2:11][C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:25]1=[O:26])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 2346Benzyl IsothiocyanateHCID 3283Diethyl EtherHCID 49908342-Benzylphenyl isocyanate

Product 1

HCID 11523651HCID 11523651, compound

Procedure

Reagents: Benzylisothiocyanate (6.5 mmol, 0.85 mL), 2-benzylphenyl-isocyanate (6.5 mmol, 0.82 mL) and SO2Cl2 (6.5 mmol, 0.5 mL) in diethyl ether (25 mL). Isolation: filtration of reaction mixture. Purification: recrystallization from EtOH

Workup

  1. filtrationIsolation: filtration of reaction mixture
  2. customPurification
  3. customrecrystallization from EtOH

Sources & evidence

ORD record
ord-fe5172180a6e4f6aba8cc408367b2465
Source dataset
uspto-grants-2009_05
Patent number
US07531561B2

Reaction notes

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