HRID49362

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CC/C(=C\CCC(O)(CC)CC)c1csc(COc2ccc(CO[Si](C)(C)C(C)(C)C)c(CO[Si](C)(C)C(C)(C)C)c2)c1$

HCID69825106

未命名化合物

PRODUCTS

生成物

$结构：CC/C(=C\CCC(O)(CC)CC)c1csc(COc2ccc(CO)c(CO)c2)c1$

HCID69825176

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID74236

未命名化合物

PROCEDURE

实验过程

In a manner similar to that of Example 6(l), by reaction of 1 g (1.5 mmol) of (E)-7-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-3-thienyl}-3-ethylnon-6-en-3-ol with 3.7 mL (3.7 mmol) of 1.0 M tetrabutylammonium bromide, the desired product is obtained in the form of white crystals (m.p.=73-74° C.; m=480 mg; Y=74%).