HuagongsheHuagongshe Chemistry Print Report · For research reference only
(3E,5E)-6-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-2-thienyl}-1,1,1-trifluoro-2-trifluoromethylocta-3,5-dien-2-ol → HCID 86759391, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (3E,5E)-6-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-2-thienyl}-1,1,1-trifluoro-2-trifluoromethylocta-3,5-dien-2-ol | HCID 88011818 | — |
| Catalyst | Tetrabutylammonium Bromide | HCID 74236 | — |
| Product | HCID 86759391 | HCID 86759391 | — |
Reaction Steps
In a manner similar to that of Example 6(l), by reaction of 200 mg of (3E,5E)-6-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-2-thienyl}-1,1,1-trifluoro-2-trifluoromethylocta-3,5-dien-2-ol with 700 μL (0.7 mmol) of 1.0 M tetrabutylammonium bromide, the desired product is obtained in the form of white crystals (m.p.=113-114° C.; m=70 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06706725B1 |
| Source dataset | uspto-grants-2004_03 |
| ORD ID | ord-3bb37f5d8ff641d7b8a15d54ca1c6800 |
| Source note | uspto-grants-2004_03 |