HRID49368

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID21226445

未命名化合物

$结构：CCOC(=O)/C=C(\CC)c1csc(COc2ccc(CO[Si](C)(C)C(C)(C)C)c(CO[Si](C)(C)C(C)(C)C)c2)c1$

HCID131724377

未命名化合物

PRODUCTS

生成物

$结构：CC/C(=C\CO)c1csc(COc2ccc(CO[Si](C)(C)C(C)(C)C)c(CO[Si](C)(C)C(C)(C)C)c2)c1$

HCID69824522

未命名化合物

收率 100%

PROCEDURE

实验过程

In a manner similar to that of Example 7(b), by reaction of 2.3 g (3.8 mmol) of ethyl (E)-3-{5-[3,4-bis(tert-butyldimethylsilanyloxymethyl)phenoxymethyl]-3-thienyl}-2-pentenoate with 180 mg (4.7 mmol) of lithium aluminium hydride, the desired product (m=2.1 g; Y=100%) is obtained in the form of a colourless oil.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-be7615b2cedd4f71a251c7078e0c4b12
来源数据集: uspto-grants-2004_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06706725B1
来源说明: uspto-grants-2004_03

反应 SMILES

[Si:1]([O:8][CH2:9][C:10]1[CH:11]=[C:12]([CH:29]=[CH:30][C:31]=1[CH2:32][O:33][Si:34]([C:37]([CH3:40])([CH3:39])[CH3:38])([CH3:36])[CH3:35])[O:13][CH2:14][C:15]1[S:19][CH:18]=[C:17](/[C:20](/[CH2:27][CH3:28])=[CH:21]/[C:22](OCC)=[O:23])[CH:16]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[Si:1]([O:8][CH2:9][C:10]1[CH:11]=[C:12]([CH:29]=[CH:30][C:31]=1[CH2:32][O:33][Si:34]([C:37]([CH3:38])([CH3:40])[CH3:39])([CH3:35])[CH3:36])[O:13][CH2:14][C:15]1[S:19][CH:18]=[C:17](/[C:20](/[CH2:27][CH3:28])=[CH:21]/[CH2:22][OH:23])[CH:16]=1)([C:4]([CH3:6])([CH3:5])[CH3:7])([CH3:3])[CH3:2]